Monel 400

Material Data Sheet

Monel® 400 is a nickel-copper alloy (about 67% Ni – 23% Cu) that is resistant to seawater and steam at high temperatures as well as to salt and caustic solutions. Monel® 400 is a solid solution alloy that can only be hardened by cold working. This nickel alloy exhibits characteristics like good corrosion resistance, good wearability, and high strength. A low corrosion rate in rapidly flowing brackish or seawater combined with excellent resistance to stress-corrosion cracking in most freshwaters, and its resistance to a variety of corrosive conditions led to Monel® 400’s wide use in marine applications and other non-oxidizing chloride solutions. This nickel alloy is particularly resistant to hydrochloric and hydrofluoric acids when they are de-aerated. As would be expected from its high copper content, Monel® 400 is rapidly attacked by nitric acid and ammonia systems.

Monel® 400 has great mechanical properties at subzero temperatures, can be used in temperatures up to 1000° F, and its melting point is 2370-2460° F. However, alloy 400 is low in strength in the annealed condition so, a variety of tempers may be used to increase the strength.

Monel® 400 can easily be welded by gas-tungsten arc, gas metal arc, or shielded metal arc processes using appropriate filler metals. There is no need for post-weld heat treatment, however, thorough cleaning after welding is critical for optimum corrosion resistance, otherwise, there is the risk of contamination and embrittlement. Finished fabrications can be produced to a wide range of mechanical properties when proper control of the amount of hot or cold working and the selection of appropriate thermal treatments is done.

Like most other nickel alloys, Monel® 400 is typically tough to machine and will work harden. However, excellent results can be obtained if you make the correct choices for tooling and machining.

Chemical Composition
Element Content (%)
Nickel, Ni 64.0
Copper, Cu 31.0
Iron, Fe ≤ 2.5
Manganese, Mn ≤ 2.0
Silicon, Si ≤ 0.5
Carbon, C ≤ 0.3
Sulphur, S ≤ 0.02
Physical Properties
Properties Metric Imperial
Density 8.8 gm/cm3 0.318 lb/in3
Melting Point 1300 – 1350 °C 2370 – 2460 °F
Mechanical Properties
Properties Metric Imperial
Tensile strength (annealed) 517-620 MPa 75-90 ksi
Yield strength 172-345 MPa 25-50 ksi
Modulus of elasticity 179 GPa 26000 ksi
Poisson’s ratio 0.32 0.32
Applications
  • Marine engineering
  • Chemical and hydrocarbon processing equipment
  • Gasoline and freshwater tanks
  • Crude petroleum stills
  • De-aerating heaters
  • Boiler feed water heaters and other heat exchangers
  • Valves, pumps, shafts, fittings, and fasteners
  • Industrial heat exchangers
  • Chlorinated solvents
  • Crude oil distillation towers
Specifications
  • AMS 4574
  • AMS 4675
  • AMS 4731
  • ASTM B163
  • ASTM B165
  • ASTM F96
  • UNS N04400

Key Words: AFNOR NU30; SAE AMS 4544, 4574, 4575, 4675, 4730, 4731, 7233; DIN 17743, 17750 – 17754, ASME SB-127, SB-163 – SB-165, SB-564, Boiler Code Sections III, IV, VIII, IX; AECMA Pr EN 2305, Monel Nickel-Copper Alloy, UNS N04400; BS 3072-3076 (NA 13); ASTM B 127, B 163 – B 165, B 564, Werkstoff Nr. 2.4360, 2.4361; VdTUV 263; MIL-T-1368, MIL-T-23520, MIL-N-24106; QQ-N-281; NACE MR-01-75

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